PAHs in the monsoonal open ocean: Homogeneous spatial pattern and wind-driven significant seasonal variations

PAHs enter the ocean via surface runoff and atmospheric transport pathways, and the distribution of PAHs is highly variable in coastal seas due to the influence of direct human activities, inputs of surface runoff, and strong biological activities. However, highly temporal variability of PAHs has also been widely observed in the open oligotrophic tropical and subtropical oceans without the influence of three types of factors mentioned above. This study developed a method to quantify the variability of oceanic PAHs based on wind frequency and wind-speed-weighted wind frequency using in-situ survey data from three cruises in the Philippine Sea, and tested the validity of this method using publicly available data from other monsoonal open oceans. The result showed that the wind frequency could better explain the variation of dissolved PAHs and particulate PAHs in the surface ocean, while the wind-speed-weighted wind frequency could better explain the variation of particulate PAHs. This study suggests that the influence of seasonal atmospheric transport cannot be ignored when describing and interpreting the distribution patterns of PAHs in the monsoon-influenced low and mid-latitude open oceans and also provides a reference method for a better understanding of the global-scale distribution patterns of PAHs in the ocean.