An approach for carbon content measurement in marine sediment: Application of organic and elemental carbon analyzer

Organic and Elemental Carbon (OEC) is widely applied in the atmospheric sciences for determining carbon content and distinguishing black carbon contents of aerosols, with an advantage that OEC-based approach can provide thermograms derived from carbonaceous material. It is potential to adopt the advantage to measure the content and composition of organic carbon (OC)% in marine sediments. Here, we utilized the OEC analyzer to measure the OC% in marine sediment based on the pyrolytic oxidation principle, and obtain the OC-derived carbon dioxide (CO₂) thermograms. We examined marine sediments and reference materials to understand the stability and reproducibility of OC% measurements using our approach. The findings indicate that the OC% results (ranging from 1.44 to 1.59%, ave. 1.55 ± 0.03%, n = 64) based on this approach are accurate. In addition, CO₂ concentration thermograms obtained by repeated measurements exhibit a strong reproducibility. Our approach can thus provide the concentrations of thermally-evolved CO₂ with increasing heating temperature to deeply understand the reactivities of OC and the compositions in sediments. We suggest that the OEC-based OC% measurement is credible when samples preparation is well-performed (e.g., suitable sample mass and uniformly distributed loading). To sum up, we provide a means to accurately determine the OC% in marine sediments in terms of the ramped-pyrolysis principle.