A green and multi-win strategy for coal fly ash disposal by CO2 fixation and mesoporous silica synthesis

Coal combustion provides plenty of energy, along with enormous coal fly ash (CFA) and CO₂ emission. CFA could be recycled for mesoporous silica synthesis, but expensive templates are usually needed. In this work, we proposed a multi-win strategy using CO₂ as the precipitator and template. Mesoporous silica powders, with a maximum specific surface area of 355.45 m²/g, a pore volume of 0.73 cm³/g, and an average pore size of around 7.67 nm, were synthesized. The influences of silicon concentration, CO₂ flow rate, and ultrasound were investigated. In addition, the Na₂CO₃ by-product was produced with a purity of over 92 %. By averagely calculating, 1 ton CFA could generate 285 kg mesoporous silica and 1.02 t crude Na₂CO₃. Around 433 kg of CO₂ could be absorbed. Therefore, multi-goals of CFA disposal, CO₂ storage, and valuable silica materials production were realized, and the study could pave the way for large-scale industrial applications.