Dynamic evolution of the active center driven by hemilabile coordination in Cu/CeO2 single-atom catalyst

Zheng Chen1, Zhangyun Liu1, Xin Xu2,3

  • 1Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, MOE Key Laboratory of Computational Physical Sciences, Department of Chemistry, Fudan University, Shanghai, 200433, P. R. China.

Summary

Hemilability, a concept from homogeneous catalysis, is now shown to enhance heterogeneous single atom catalysts. Dynamic metal-support interactions tune active sites, boosting catalytic activity for reactions like CO oxidation.

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