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Updated: Jul 31, 2025

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Characterization of the dynamic stretching stages of polymeric fibers using dispersion measurements
Abstract:
In this paper, we characterize the dynamics of the molecular chains at different stages of stretching polymeric monofilament fibers. The main stages characterized in this work are shear-bands, necking, crazes, cracks, and fracture regions. Digital photoelasticity and white-light two-beam interferometry are utilized to study each phenomenon by finding the dispersion curves and the 3D birefringence profiles using a single-shot pattern, which is performed for the first time, to our best knowledge. We also suggest an equation to find the full-field distribution of the oscillation energy. This study presents a clear vision on the behavior of the polymeric fibers at a molecular level during dynamic stretching until reaching its fracture point. Patterns of these deformation stages are given for illustration.
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