Preparation and Evaluation of Co-Doped Fe₇S₈/C Composites for Lithium Storage

Fe₇S₈ has a high theoretical capacity (663 mAh g^-1) and can be prepared at a low cost, making it advantageous for production. However, Fe₇S₈ has two disadvantages as a lithium-ion battery anode material. The first is that the conductivity of Fe₇S₈ is not good. The second is that when the lithium ion is embedded, the volume expansion of the Fe₇S₈ electrode is serious. That is why Fe₇S₈ has not been used in real life yet. In this paper, Co-Fe₇S₈/C composites were prepared by doping Co into Fe₇S₈ through a one-pot simple hydrothermal method. In situ Co is doped into Fe₇S₈ to produce a more disordered microstructure to improve ion and electron transport performance, thereby reducing the activation barrier of the main material. The Co-Fe₇S₈/C electrode presents a high specific discharge capacity of 1586 mAh g^-1 and a Coulombic efficiency (CE) of 71.34% at an initial cycle at 0.1 A g^-1. After 1500 cycles, the specific discharge capacity remains at 436 mAh g^-1 (5 A g^-1). When the current density returns to 0.1 A g^-1, the capacity almost returns to the initial level, showing excellent rate performance.