Unveiling the migration of Cr and Cd to biochar from pyrolysis of manure and sludge using machine learning

Heavy metal (HM) in biochar derived from pyrolysis of sludge or manure is the main issue for its large-scale application in soils for carbon sequestration. However, there is a paucity of efficient approaches to predict and comprehend the HM migration during pyrolysis for preparing low HM-contained biochar. Herein, the data on the feedstock information (FI), additive, total concentration of feedstock (FTC) of HM (i.e., Cr and Cd), and pyrolysis condition, were extracted from the literature, to predict total concentration (TC) and retention rate (RR) of Cr and Cd in sludge/manure biochar using machine learning for mapping their migration during pyrolysis. Two datasets for Cr and Cd were compiled with 388 and 292 data points from 48 and 37 peer-review papers. The results indicated that the TC and RR of Cr and Cd could be predicted by the Random Forest model with test R² of 0.74-0.98. Their TC and RR in biochar were dominated by the FTC and FI, respectively; while pyrolysis temperature was the most important to Cd RR. Moreover, potassium-based inorganic additives decreased the TC and RR of Cr while increased those of Cd. The predictive models and insights provided by this work could aid the understanding of HM migration during manure and sludge pyrolysis and guide the preparation of low HM-contained biochar.