Enhanced selective separation of vanadium(V) and chromium(VI) using the CeO₂ nanorod containing oxygen vacancies

Adsorption of vanadium from wastewater defends the environment from toxic ions and contributes to recover the valuable metal. However, it is still challenging for the separation of vanadium (V⁵⁺) and chromium (Cr⁶⁺) because of their similar properties. Herein, a kind of CeO₂ nanorod containing oxygen vacancies is facilely synthesized which displays ultra-high selectivity of V⁵⁺ against various competitive ions (i.e., Fe, Mn, Cr, Ni, Cu, Zn, Ga, Cd, Ba, Pb, Mg, Be, and Co). Moreover, a large separation factor (SF_V/Cr) of 114,169.14 for the selectivity of V⁵⁺ is achieved at the Cr⁶⁺/V⁵⁺ ratio of 80 with the trace amount of V⁵⁺ (~ 1 mg/L). The results show that the process of V⁵⁺ uptake is the monolayer homogeneous adsorption and is controlled by external and intraparticle diffusions. In addition, it also shows that V⁵⁺ is reduced to V³⁺ and V⁴⁺ and then formation of V-O complexation. This work offers a novel CeO₂ nanorod material for efficient separation of V⁵⁺ and Cr⁶⁺ and also clarifies the mechanism of the V⁵⁺ adsorption on the CeO₂ surface.