Ti₃ C₂ T_X MXene Ink Direct Writing Flexible Sensors for Disposable Paper Toys

Flexible electronics have gained great attention in recent years owing to their promising applications in biomedicine, sustainable energy, human-machine interaction, and toys for children. Paper mainly produced from cellulose fibers is attractive substrate for flexible electronics because it is biodegradable, foldable, tailorable, and light-weight. Inspired by daily handwriting, the rapid prototyping of sensing devices with arbitrary patterns can be achieved by directly drawing conductive inks on flat or curved paper surfaces; this provides huge freedom for children to design and integrate "do-it-yourself (DIY)" electronic toys. Herein, viscous and additive-free ink made from Ti₃ C₂ T_X MXene sediment is employed to prepare disposable paper electronics through a simple ball pen drawing. The as-drawn paper sensors possess hierarchical microstructures with interweaving nanosheets, nanoflakes, and nanoparticles, therefore exhibiting superior mechanosensing performances to those based on single/fewer-layer MXene nanosheets. As proof-of-concept applications, several popular children's games are implemented by the MXene-based paper sensors, including "You say, I guess," "Emotional expression," "Rock-Paper-Scissors," "Arm wrestling," "Throwing game," "Carrot squat," and "Grab the cup," as well as a DIY smart whisker for a cartoon mouse. Moreover, MXene-based paper sensors are safe and disposable, free from producing any e-waste and hazard to the environment.