Chitosan-g-polyacrylonitrile ZnO nano-composite, synthesis and characterization as new and good adsorbent for Iron...

The highly poisonous, non-biodegradable heavy metals present serious concern in wastewater environmental sustainability and human health. Using adsorption is an effective technology for the treatment of this kind of water. Therefore, developing efficient and cost-effective adsorbents considers a significant and an emerging topic in the field the water purification. Chitosan grafted polyacrylonitrile (Cs-g-PAN) was facially fabricated via graft polymerization using ammonium persulfate (APS) as the initiator. The simple ultrasonic technique was used for doping ZnO nanoparticles into the Cs-g-PAN matrix to prepare chitosan-grafted polyacrylonitrile/ZnO (Cs-g-PAN/ZnO). For comparative study, pure ZnO and nanocomposite of PAN doped with ZnO (PAN/ZnO) were also prepared. XRD, FTIR, SEM, TEM, BET, EDS, and TGA measurements were conducted to confirm the morphological and structural properties of the prepared materials. Cs-g-PAN/ZnO possesses a specific surface area of 20.23 m²/g with a pore size of 31.58 nm and pore volume of 0.16 cm³ g^-1. The adsorption behavior toward Fe(II) as a pollutant for groundwater was studied for the synthesized materials. The effect of pH (4-8), contact time (5-60 min), adsorbent dose (0.01-0.3 g), and different temperature degrees (278, 288, 298, 308, and 318 K) on the removal of iron (II) has been conducted. The removal efficiency was achieved 100 % under the optimum condition, at pH = 7, contact time 30 min, adsorbate concentration 0.93 mg/L, and adsorbent dosage 0.05 g/L at room temperature. Langmuir and Freundlich's isothermal and kinetic studies have been analyzed to determine the adsorption mechanism of Fe(II) ions on the synthesized nanomaterials. The adsorption process of Fe(II) over the surface of prepared catalysts proceeded via the Langmuir model and pseudo-second-order reaction kinetics with R² > 0.99. Suggesting the formation of Fe(II) monolayer over the adsorbent surface and the rate-limiting step is probably controlled by chemisorption through sharing the electrons between Fe⁺² and the prepared catalyst.