Control of phosphorus release from sediment by hydrous zirconium oxide combined with calcite, bentonite and zeolite

This study investigated the effectiveness and mechanism for the control of internal phosphorus (P) liberation from sediment by hydrous zirconium oxide (HZrO₂) combined with calcite, bentonite and zeolite. The results suggested that coexisting calcite, calcium-modified bentonite (CaBT) and calcium-modified zeolite (CaZ) all had the ability to promote the adsorption of phosphate (PO₄^3-) onto HZrO₂. The mechanisms of PO₄^3- elimination by HZrO₂/calcite mixture involved the adsorption of PO₄^3- on calcite, the precipitation of PO₄^3- with Ca²⁺, and the inner-sphere complexation of PO₄^3- with HZrO₂. The amendment of sediment with HZrO₂/calcite, HZrO₂/CaBT or HZrO₂/CaZ mixture can effectively prevent the sedimentary P release, and the immobilization of mobile P in the sediment and the uptake of dissolved reactive P (DRP) from the interstitial water by the amendment material played a key role in the control of P release from sediment by the combined amendment. Capping sediment with HZrO₂/calcite, HZrO₂/CaBT or HZrO₂/CaZ mixture also can effectively intercept sediment P release, and the formation of P static layer attributed to the uptake of interstitial water DRP and DGT (diffusive gradient in thin-films)-unstable P in the upper sediment by the capping material was a key to the inhibition of sedimentary P migration into the overlying water by the combined capping. The great majority of P immobilized by the HZrO₂/calcite, HZrO₂/CaBT or HZrO₂/CaZ combined covering layer is stable P and it has a low re-releasing risk under dissolved oxygen-deficit and pH 5-9 condition. The stability of P bound by the combined covering layer was larger than that by the single HZrO₂ covering layer. The results of this research show that the combined use of HZrO₂ and calcite, HZrO₂ and CaBT, or HZrO₂ and CaZ as a capping material has great potential in the reduction of sediment P loading.