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Tailoring cavity coupled plasmonic substrates for SERS applications.

Jagathpriya L M1, Jayakumar Pillanagrovi1, Shourya Dutta-Gupta1

  • 1Materials Science and Metallurgical Engineering, Indian Institute of Technology Hyderabad, Hyderabad, India.

Nanotechnology
|May 12, 2023
PubMed
Summary

We developed a novel cavity-coupled plasmonic substrate that significantly enhances light-matter interactions for improved Surface-Enhanced Raman Spectroscopy (SERS) performance. This low-cost, large-area technique offers a nearly 9x enhancement in SERS signals.

Keywords:
SERScavity-couplinggold nanoparticlesplasmonicssensing

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Area of Science:

  • Plasmonics
  • Nanotechnology
  • Spectroscopy

Background:

  • Surface-enhanced Raman spectroscopy (SERS) offers high sensitivity and specificity for biosensing.
  • Optimizing light coupling into plasmonic nanostructures is key to enhancing SERS substrate performance.
  • Engineered substrates are needed to improve light-matter interactions for advanced SERS applications.

Purpose of the Study:

  • To demonstrate a cavity-coupled structure for enhanced light-matter interaction and improved SERS performance.
  • To investigate the influence of cavity length and wavelength on SERS signal modulation.
  • To fabricate and characterize cost-effective, large-area cavity-coupled plasmonic substrates.

Main Methods:

  • Numerical simulations were employed to model the optical properties of cavity-coupled structures.
  • Fabrication of substrates involved depositing gold nanospheres onto indium tin oxide (ITO)-Au-glass layers.
  • Experimental characterization of SERS enhancement was performed using the fabricated substrates.

Main Results:

  • Cavity-coupled structures demonstrated the ability to enhance or suppress SERS signals based on design parameters.
  • Simulations predicted tunable SERS signal modulation with cavity length and wavelength.
  • Fabricated substrates showed a nearly 9-fold improvement in SERS enhancement compared to uncoupled designs.

Conclusions:

  • The cavity-coupling approach effectively enhances light-matter interactions for superior SERS performance.
  • Low-cost, large-area fabrication methods are viable for producing these advanced plasmonic substrates.
  • This technique holds potential for improving other plasmonic phenomena, including trapping, catalysis, and nonlinear signal generation.