3D printed bio-ceramic loaded PEGDA/vitreous carbon composite: Fabrication, characterization, and life cycle...

Stereolithography (SLA) is gaining vast popularity in the development of three-dimensional parts with customized materials for tissue engineering applications. Consequently, developing customized materials like bio-composites (bio-polymers and bio-ceramics) is the basic pillar that meets the application requirement. Photo-crosslinkable poly(ethylene glycol) diacrylate (PEGDA) has outstanding biocompatibility and biophysical properties for tissue engineering. But, because of its poor mechanical properties, its scope is limited to load-bearing applications. This research aims to enhance the mechanical and tribological properties of PEGDA by reinforcing Vitreous Carbon (VC) bioceramic. Therefore, 1 to 5 wt % of VC have been added in PEGDA and developed novel PEGDA/VC composite resins for SLA. The rheological and sedimentation test have been performed to check the suitability for SLA printing. Afterward, printed materials have been characterized by fourier transform infrared spectrometer, X-ray diffraction, thermogravimetric analysis, optical profilometer, and scanning electron microscope. Moreover, tensile compression, flexural, and tribological properties have been evaluated. It was found that the addition of VC in PEGDA enhanced its mechanical, thermal, and tribological properties. Besides, a life cycle assessment of materials and energy resources in SLA process has been performed to investigate the environmental impact.