Microwave solvothermal synthesis of Component-Tunable High-Entropy oxides as High-Efficient and stable...

Transition-metal-based high-entropy oxides (HEOs) are appealing electrocatalysts for oxygen evolution reaction (OER) due to their unique structure, variable composition and electronic structure, outstanding electrocatalytic activity and stability. Herein, we propose a scalable high-efficiency microwave solvothermal strategy to fabricate HEO nano-catalysts with five earth-abundant metal elements (Fe, Co, Ni, Cr, and Mn) and tailor the component ratio to enhance the catalytic performance. (FeCoNi₂CrMn)₃O₄ with a double Ni content exhibits the best electrocatalytic performance for OER, namely low overpotential (260 mV@10 mA cm^-2), small Tafel slope and superb long-term durability without obvious potential change after 95 h in 1 M KOH. The extraordinary performance of (FeCoNi₂CrMn)₃O₄ can be attributed to the large active surface area profiting from the nano structure, the optimized surface electronic state with high conductivity and suitable adsorption to intermediate benefitting from ingenious multiple-element synergistic effects, and the inherent structural stability of the high-entropy system. In addition, the obvious pH value dependable character and TMA⁺ inhibition phenomenon reveal that the lattice oxygen mediated mechanism (LOM) work together with adsorbate evolution mechanism (AEM) in the catalytic process of OER with the HEO catalyst. This strategy provides a new approach for the rapid synthesis of high-entropy oxide and inspires more rational designs of high-efficient electrocatalysts.