Polychromatic fluorescent MoS₂ quantum dots: fabrication and off-on sensing for fluorine ions in water

Recently, MoS₂ quantum dots (QDs) have receive widespread attention as a promising luminescent material. However, so far, little effort has been made on the multicolor emission of MoS₂ QDs. Herein, an in situ iodine doping strategy is presented and used to synthesize tunable-photoluminescent (PL) MoS₂ QDs. By fine iodine doping, the PL of the MoS₂ QDs (I-MoS₂ QDs) can be tuned in the range from 423 nm to 529 nm, which exceeds the as-reported emission wavelength range. Studies using controlled experiments and density functional theory (DFT) reveal that the change in electronic state of MoS₂ QDs is responsible for the changing PL due to iodine doping. As-synthesized I-MoS₂ QDs combined with Fe³⁺ is developed as a "turn-off-on" fluorescence sensor for F^- ions in water. The fluorescence probe has a fine linear response to F^- ions in the concentration range of 2.5-80 μM, and the limit of detection is 1.4 μM (S/N = 3).