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Updated: Jul 30, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Published on: November 21, 2017

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Escape from Palladium: Nickel-Catalyzed Catellani Annulation

Jingfeng Huo1, Yue Fu2, Melody J Tang1

  • 1Department of Chemistry, University of Chicago, Chicago, Illinois 60637, United States.

Journal of the American Chemical Society
|May 15, 2023
PubMed
Summary

This study introduces the first nickel-catalyzed Catellani-type reaction for arene functionalization, efficiently creating benzocyclobutene-fused norbornanes. The novel nickel catalysis offers improved regioselectivity and functional group tolerance compared to palladium methods.

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