Competitive adsorption of lead and cadmium onto nanoplastics with different charges: Two-dimensional correlation...

The competitive adsorption ability and mechanisms of lead (Pb²⁺) and cadmium (Cd²⁺) by nanoplastics (NPs) with positive charges (PS-NH₂) and negative charges (PS-SO₃H) were investigated by using batch adsorption experiments coupled with the two-dimensional correlation spectroscopy (2D-COS) method. The adsorption isotherm results showed that PS-SO₃H exhibited a higher adsorption capacity for Pb²⁺ or Cd²⁺ compared to PS-NH₂. The adsorption affinity of NPs for Pb²⁺ was higher than that of Cd²⁺. The competitive adsorption results showed that Pb²⁺ had a more pronounced negative effect on the adsorption of Cd²⁺. The adsorption capacities of NPs were affected by the surface charge and solution pH. Electrostatic force was the main factor influencing PS-SO₃H to capture Pb²⁺ and Cd²⁺, while chelation was the main mechanism between PS-NH₂ and metals. The functional groups of NPs played significant roles in the sorption of Pb²⁺ or Cd²⁺ according to the FTIR spectra and 2D-COS analysis. This study provided new insights into the impact of NPs on the transport of other pollutants.