Modulating Lewis acidic active sites of Fe doped Bi₂MoO₆ nanosheets for enhanced electrochemical nitrogen fixation

Electrocatalytic nitrogen reduction reaction (NRR) for artificial ammonia synthesis under mild conditions has been considered as a promising alternative to the conventional Haber-Bosch method. The highly desired efficient NRR still faced with the mulriple challenges of adsorption and activation of N₂ and limited Faraday efficiency. Here, Fe-doped Bi₂MoO₆ nanosheets fabricated by one step synthesis exhibits high NH₃ yield rate of 71.01 μg·h^-1·mg^-1 and Faraday Efficiency of 80.12%. The decreased electron density of Bi in collaboration with Lewis acid active sites on Fe-doped Bi₂MoO₆, jointly enhance the adsorption and activation of Lewis basic N₂. Benefited from surface texture optimization and the superior ability of N₂ adsorption and activation, the increasing density of effective active sites greatly improve the NRR behavior. This work provides new opportunities for developing efficient and highly selective catalysts for NH₃ synthesis via NRR.