Preparation of cationic aggregates derived from sewage sludge for efficient capture of organic matter

Capturing the abundant organic matter residing in wastewater can not only reduce the emission of CO₂ from the source, but the enriched organics can also be used for anaerobic fermentation to generate and offset energy consumption in wastewater treatment processes. The key is to find or develop low-cost materials that can capture organic matter. Herein, sewage sludge-derived cationic aggregates (SBC-g-DMC) were successfully prepared via a hydrothermal carbonization process coupled with a graft copolymerization reaction for recovering organic matter from wastewater. Based upon preliminary screening of synthesized SBC-g-DMC aggregates regarding grafting rate, cationic degree, and flocculation performance, SBC-g-DMC_2.5 aggregate prepared with 60 mg of initiator, DMC-to-SBC mass ratio of 2.5:1, 70 °C, and 2 h of reaction time was selected for further characterization and evaluation. Results showed that SBC-g-DMC_2.5 aggregate has a positively-charged surface over a wide pH range of 3-11 and a hierarchical micro-/nano-structure, endowing it with an excellent organic matter capture efficiency (97.2% of pCOD, 68.8% of cCOD, and 71.2% of tCOD). Meanwhile, SBC-g-DMC_2.5 exhibits inappreciable trapping ability for the dissolved COD, NH₃-N, and PO₄^3-, guaranteeing the regular running of subsequent biological treatment units. Electronic neutralization, adsorption bridging, and sweep coagulation between cationic aggregates surface and organic matter were identified as the primary mechanisms for SBC-g-DMC_2.5 to capture organics. This development is expected to provide a theoretical reference for sewage sludge disposal, carbon reduction, and energy recovery during municipal wastewater treatment.