Direct visualization of carbon black aggregates in nitrile butadiene rubber by THz near-field microscope

The use of filling agents for rubber reinforcement is beneficial in various industrial applications, and several experimental methods have been used to study the effect of fillers on rubber. However, due to the lack of a suitable imaging technique, filler dispersion and distribution in rubber cannot be easily displayed. Thus, we utilize the THz near-field microscope (THz-NFM) to directly visualize the distribution of carbon black (CB) aggregates in nitrile butadiene rubber (NBR). The THz time-domain spectroscopy (THz-TDS) was used to evaluate the optical properties of the NBR specimens. Results revealed significant indices contrast between CB and NBR at the THz regime, which was attributed to the variation in electrical conductivities. The micrographs of NBR in the THz-NFM revealed the distribution of CB aggregates. The area fraction (AF) of the CB aggregates was calculated using a binary thresholding algorithm to compare with the transmission electron microscope method. Both methods yielded comparable AF values, suggesting, for the first time, that CB can be detected in the NBR without preprocessing the specimens.