Controllable hydrogen-bonded poly(dimethylsiloxane) (PDMS) membranes for ultrafast alcohol recovery

The lack of efficient separation membranes limits the development of bio-alcohol purification via a pervaporation process. In this work, novel controllable hydrogen-bonded poly(dimethylsiloxane) (PDMS) membranes are prepared from self-synthesized supramolecular elastomers for alcohol recovery. Different from the conventional covalently-bonded PDMS membranes, the hydrogen-bonding content and therefore the crosslinking degree in the as-synthesized PDMS membranes can be exactly regulated, by the suitable molecular design of the supramolecular elastomers. The effects of hydrogen-bonding content on the flexibility of the polymer chains and the separation performance of the resultant supramolecular membranes are investigated in detail. In comparison with the state-of-the-art polymeric membranes, the novel controllable hydrogen-bonded supramolecular PDMS membrane exhibits ultrahigh fluxes for ethanol (4.1 kg m^-2 h^-1) and n-butanol (7.7 kg m^-2 h^-1) recovery from 5 wt% alcohol aqueous solutions at 80 °C, with comparable separation factors. The designed supramolecular elastomer is therefore believed to provide valuable insights into the design of next-generation separation membrane materials for molecular separations.