Ratiometric fluorescent sensor based on metal-organic framework for selective and sensitive detection of CO₃²

Carbonate ion (CO₃^2-) is an anion essential for the maintenance of life activities and is of great importance to human health. Here, a novel ratiometric fluorescent probe Eu/CDs@UiO-66-(COOH)₂ (ECU) was prepared by introducing europium ions (Eu³⁺) and carbon dots (CDs) into the UiO-66-(COOH)₂ parent framework under the guidance of a post-synthetic modification strategy and used for the detection of CO₃^2- ion in the aqueous environment. Interestingly, when CO₃^2- ions were added to the ECU suspension, the characteristic emission of carbon dots at 439 nm was significantly enhanced, while the characteristic emission of Eu³⁺ ions at 613 nm was reduced. Therefore, the detection of CO₃^2- ions can be realized through the peak height ratio of the two emissions. The probe had a low detection limit (about 1.08 μM) and a wide linear range (0-350 μM) for the detection of carbonate. In addition, the presence of CO₃^2- ions can cause a significant ratiometric luminescence response and resulted obvious red-to-blue color shift of the ECU under UV light, which will facilitate visual analysis by the naked eye.