Efficient removal of heavy metals from aqueous solutions using Mn-doped FeOOH: Performance and mechanisms

The treatment of heavy metal ion contamination in aquatic ecosystems has been a growing global concern for centuries. Iron oxide nanomaterials are effective in heavy metals removal, but are frequently challenging due to the precipitation of Fe(III) and poor reusability. To improve the removal of heavy metals by iron hydroxyl oxide (FeOOH), the iron-manganese oxide material (FMBO) was separately prepared to remove Cd(II), Ni(II), and Pb(II) in individual and multiple systems. Results revealed that the loading of Mn enlarged the specific surface area and stabilized the structure of FeOOH. FMBO achieved 18%, 17%, and 40% higher removal capacities of Cd(II), Ni(II), and Pb(II) than that of FeOOH, respectively. Besides, mass spectrometry analysis demonstrated that the surface hydroxyls (-OH, Fe/Mn-OH) of FeOOH and FMBO provided the active sites for metal complexation. Fe(III) was reduced by Mn ions and further complexed with heavy metals. Further density functional theory calculations revealed that Mn loading led to the structural reconstruction of the electron transfer, which significantly promoted stable hybridization. This confirmed that FMBO improved the properties of FeOOH and was efficient for removing heavy metals from wastewater.