Iron functionalized silica particles as an ingenious sorbent for removal of fluoride from water

The paucity of safe drinking water remains a global concern. Fluoride is a pollutant prevalent in groundwater that has adverse health effects. To resolve this concern, we devised a silica-based defluoridation sorbent from pumice rock obtained from the Paka volcano in Baringo County, Kenya. The alkaline leaching technique was used to extract silica particles from pumice rock, which were subsequently modified with iron to enhance their affinity for fluoride. To assess its efficacy, selected borehole water samples were used. Scanning electron microscopy, X-ray diffraction, Fourier transform infrared and X-ray fluorescence spectroscopy was used to characterize the sorbent. The extracted silica particles were 96.71% pure and amorphous, whereas the iron-functionalized silica particles contained 93.67% SiO₂ and 2.93% Fe₂O₃. The optimal pH, sorbent dose and contact time for defluoridation of a 20 mg/L initial fluoride solution were 6, 1 g and 45 min, respectively. Defluoridation followed pseudo-second-order kinetics and fitted Freundlich's isotherm. Fluoride levels in borehole water decreased dramatically; Intex 4.57-1.13, Kadokoi 2.46-0.54 and Naudo 5.39-1.2 mg/L, indicating that the silica-based sorbent developed from low-cost, abundant and locally available pumice rock is efficient for defluoridation.