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Updated: Jul 30, 2025

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
Published on: October 31, 2019
Twist-bend nematic drops as colloidal particles: Electric instabilities.
K S Krishnamurthy1, D S Shankar Rao1, Santosh Y Khatavi1
1Centre for Nano and Soft Matter Sciences, Survey No. 7, Shivanapura, Bangalore 562162, India.
This study explores the behavior of twist-bend nematic (N_{TB}) drops in an electric field, revealing flexoelectric and electrokinetic responses. These drops exhibit unique movements and alignments, offering insights into liquid crystal dynamics.
Area of Science:
- Liquid Crystal Physics
- Soft Matter Science
- Materials Science
Background:
- The study investigates the mesogen 1,''7''-bis(4-cyanobiphenyl-4'-yl)heptane (CB7CB) doped with an amphiphilic compound.
- Focuses on the biphasic state where twist-bend nematic (N_{TB}) drops are dispersed in an isotropic fluid.
Purpose of the Study:
- To examine the flexoelectric and electrokinetic responses of N_{TB} drops in various geometries (escaped-radial-like and parabolic focal conic defects).
- To understand the influence of low-frequency electric fields on N_{TB} drop behavior, including dimensional changes and core relocations.
- To elucidate the electrohydrodynamic effects and hydrodynamic flows within N_{TB} drops under varying electric field conditions.
Main Methods:
- Experimental observation of N_{TB} drops under applied low-frequency electric fields.
- Analysis of drop geometry, defect structures (confocal parabolas, hedgehog core), and alignment.
- Characterization of translatory motion and vortical flows using principles like the Taylor-Melcher leaky dielectric model.
Main Results:
- Periodic dimensional changes in drops with parabolic focal conic defects contribute to flexoelectric free-energy reduction.
- In escaped-radial-like (ER) droplets, flexoelectric effects are achieved through hedgehog core relocations.
- ER drops exhibit field-dependent translatory motion (velocity quadratic in field strength) over a broad frequency range (dc to MHz), with direction reversal at a critical frequency.
- Patterned states and homeotropic alignment are observed at different field strengths and voltage crossings.
- Vortical flows become discernible in ER drops at high electric fields.
Conclusions:
- N_{TB} drops display complex flexoelectric and electrokinetic behaviors in response to electric fields.
- The geometry of the drops, particularly off-centered configurations, plays a crucial role in enabling electrohydrodynamic effects.
- The study provides a detailed understanding of the dynamic responses of N_{TB} drops, relevant for liquid crystal display and microfluidic applications.
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