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Band splitting and enhanced charge density wave modulation in Mn-implanted CsV3Sb5.

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Manganese doping in Kagome metal CsV3Sb5 enhances charge density waves (CDW) and topological states. Ion implantation creates Mn-doped crystals, revealing band splitting and a higher CDW transition temperature.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Quantum Materials

Background:

  • Kagome metal CsV3Sb5 exhibits intriguing charge density wave (CDW), topological surface states, and superconductivity.
  • The interaction between magnetic doping and the exotic quantum states in CsV3Sb5 remains underexplored.

Purpose of the Study:

  • To investigate the effects of magnetic doping on the electronic properties and CDW behavior of CsV3Sb5.
  • To explore a novel method for achieving deep doping in bulk materials.

Main Methods:

  • Single crystal growth of Mn-doped CsV3Sb5 via ion implantation.
  • Angle-resolved photoemission spectroscopy (ARPES) to probe electronic band structure and CDW modulation.
  • Analysis of spectral weight transfer and magnetic ordering.

Main Results:

  • Ion implantation successfully introduced Mn doping into CsV3Sb5 single crystals.
  • Observed anisotropic band splitting across the entire Brillouin region.
  • Enhanced CDW modulation indicated by a higher Dirac cone gap closing temperature (135 K ± 5 K) compared to the bulk value (~94 K).
  • Evidence of spectral weight transfer to the Fermi level and weak antiferromagnetic order at low temperatures.

Conclusions:

  • Manganese doping significantly enhances the charge density wave (CDW) in CsV3Sb5.
  • The enhanced CDW is attributed to polariton excitation and Kondo shielding effects.
  • Ion implantation provides an effective route for deep doping in bulk materials, creating a platform for studying quantum state couplings.