A multifunctional cucurbit[6]uril-based supramolecular assembly for fluorescence sensing of TNP and Ba²⁺ and...

Both nitroaromatic compounds (NACs) and heavy metal ions are accumulative high-risk environmental pollutants, so high-sensitivity detection of these environment pollutants is necessary. In this work, a cucurbit[6]uril (CB[6]) based luminescent supramolecular assembly [Na₂K₂(CB[6])₂(DMF)₂(ANS)(H₂O)₄](1) (CB[6] = cucurbit[6]uril, ANS^2- = 8-Aminonaphthalene-1,3,6-trisulfonic acid ion) has been synthesized under solvothermal conditions, using ANS^2- as a structural inducer. Performance studies have shown that 1 exhibits excellent chemical stability and easy regeneration ability. It can highly selective sensing of 2,4,6-trinitrophenol (TNP) through fluorescence quenching with a strong quenching constant (K_sv = 2.58 × 10⁴ M^-1). Additionally, the fluorescence emission of 1 can be effectively enhanced with Ba²⁺ in aqueous solution (K_sv = 5.57 × 10³ M^-1). More impressively, Ba²⁺@1 was successfully used as anti-counterfeiting fluorescent ink functional material with strong information encryption function. This work illustrates the application prospects of luminescent CB[6]-based supramolecular assembly in environmental pollutants detection and information anti-counterfeiting for the first time, which extends the multifunctional application scope of CB[6]-based supramolecular assembly.