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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Through-Space, Lone-Pair Promoted Aromatic Substitution: A Relay Mechanism Can Beat Out Direct Activation

Muhammad Kazim1,2, Zhitao Feng3, Srini Vemulapalli4

  • 1Department of Chemistry, Johns Hopkins University, 3400 N. Charles St., Baltimore, MD 21218, USA.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|May 23, 2023
PubMed

Keywords:
density functional theoryelectrophilic substitutionfluorinenoncovalent interactionspre-complexation

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