Near-Infrared-Responsive Photocatalytic CO₂ Conversion via In Situ Generated Co₃O₄/Cu₂O

Photocatalytic CO₂ conversion to fuels is a promising strategy for achieving global carbon neutrality. However, infrared light, which accounts for ∼50% of the full sunlight spectrum, has not yet been effectively utilized via photocatalysis. Here, we present an approach to directly power photocatalytic CO₂ reduction using near-infrared light. This near-infrared light-responsive process occurs on an in situ generated Co₃O₄/Cu₂O photocatalyst with a nanobranch structure. Photoassisted Kelvin probe force microscopy and relative photocatalytic measurements demonstrate the increase of surface photovoltage after illumination by near-infrared light. We also find that Cu(I) on this in situ generated Co₃O₄/Cu₂O could facilitate the formation of a *CHO intermediate, thus enabling a high-performance CH₄ production with a yield of 6.5 μmol/h and a selectivity of 99%. Moreover, we perform a practically oriented direct solar-driven photocatalytic CO₂ reduction under concentrated sunlight and achieve a fuel yield of 12.5 μmol/h.