Alloying with Mn Enhances the Activity and Durability of the CoPt Catalyst toward the Methanol Oxidation Reaction

To improve the catalytic performance and durability of Pt catalysts used for the methanol oxidation reaction (MOR) in direct methanol fuel cells (DMFCs), alloying of Pt with other transition metals such as Ru, Co, Ni, and Fe is considered an effective approach. Despite the significant progress made in the preparation of bimetallic alloys and their utilization for MOR, improving the activity and durability of the catalysts to make them commercially viable remains a stiff challenge. In this work, trimetallic Pt_100-(MnCo) (16 < x < 41) catalysts were successfully synthesized via borohydride reduction followed by hydrothermal treatment at 150 °C. The electrocatalytic performance of the synthesized trimetallic Pt_100-(MnCo) (16 < x < 41) catalysts toward MOR was studied using cyclic voltammetry and chronoamperometry. The results affirm that all Pt_100-(MnCo) (16 < x < 41) alloys have superior MOR activity and durability as compared to bimetallic PtCo alloys and commercially available Pt/C (comm. Pt/C) catalysts. Among all the compositions studied, the Pt₆₀Mn_1.7Co_38.3/C catalyst exhibited superior mass activity (1.3 and 1.9 times higher than those of Pt₈₁Co₁₉/C and comm. Pt/C, respectively) toward MOR. Furthermore, all the newly synthesized Pt_100-(MnCo)/C (16 < x < 41) catalysts showed better CO tolerance when compared with comm. Pt/C. This improved performance of the Pt_100-(MnCo)/C (16 < x < 41) catalyst can be attributed to the synergistic effect of Co and Mn on the Pt lattice.