Enthalpy Change from Pure Cubic Ice Ic to Hexagonal Ice Ih
Christina M Tonauer1, Keishiro Yamashita1, Leonardo Del Rosso2
1Institute of Physical Chemistry, University of Innsbruck, Innrain 52c, A-6020 Innsbruck, Austria.
Abstract:
The preparation of pure cubic ice without hexagonal stacking faults has been realized only recently by del Rosso et al. ( Nat. Mater. 2020, 19, 663-668) and Komatsu et al. ( Nat. Commun. 2020, 11, 464). With our present calorimetric study on the transition from pure cubic ice to hexagonal ice we are able to clarify the value of the enthalpy change ΔHc→h to be -37.7 ± 2.3 J mol-1. The transition temperature is identified as 226 K, much higher than in previous work on ice Isd. This is due to a catalytic effect of hexagonal faults on the transition, but even more importantly due to a relaxation exotherm that was not properly identified in the past.
Related Concept Videos
Phase Transitions: Melting and Freezing
Aqueous Solutions and Heats of Hydration
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
Hess's Law
Phase Transitions: Sublimation and Deposition
Enthalpy
Heating and Cooling Curves
For instance, the addition of heat raises the temperature of a solid; the amount of heat absorbed depends on the heat capacity of the solid (q = mcsolidΔT). According to thermochemistry, the relation between the amount of heat absorbed or released by a substance, q, and its...


