Prelithiation of Lithium Peroxide for Silicon Anode: Achieving a High Activation Rate

The use of lithium peroxide (Li₂O₂) as a cost-effective low-weight prelithiation cathode additive was successfully demonstrated. Through a series of studies on the chemical stability of Li₂O₂ and the activation process of Li₂O₂ on the cathode, we revealed that Li₂O₂ is more compatible with conventional electrolyte and cathode laminate slurry than lithium oxide. Due to the significantly smaller size of commercial Li₂O₂, it can be used directly as a cathode additive. Moreover, the activation of Li₂O₂ on the cathode leads to the impedance growth of the cathode possibly resulting from the release of dioxygen and evacuation of Li₂O₂ inside the cathode. With the introduction of a new Li₂O₂ spread-coating technique on the cathode, the capacity loss was suppressed. Si||NMC full cells using Li₂O₂ spread-coated cathode demonstrated a highly promising activation rate of Li₂O₂ and significantly enhanced specific capacity and cycling stability compared to the uncoated full cells.