Surfactant Additives Containing Hydrophobic Fluorocarbon Chains and Hydrophilic Sulfonate Anion for Highly Reversible...

Aqueous zinc-ion batteries (AZIBs) show enormous potential as a large-scale energy storage technique. However, the growth of Zn dendrites and serious side reactions occurring at the Zn anode hinder the practical application of AZIBs. For the first time, we reported a fluorine-containing surfactant, i.e., potassium perfluoro-1-butanesulfonate (PPFBS), as an additive to the 2 M ZnSO₄ electrolyte. Benefitting from its hydrophilic sulfonate anion and hydrophobic long fluorocarbon chain, PPFBS can promote the uniform distribution of Zn²⁺ flux at the anode/electrolyte interface, allowing the Zn/Zn cell to cycle for 2200 h. Furthermore, PPFBS could inhibit side reactions due to the existence of the perfluorobutyl sulfonate (C₄F₉SO₃^-) adsorption layer and the presence of C₄F₉SO₃^- in the solvation structure of Zn²⁺. The former can reduce the amount of H₂O molecules and SO₄^2- in contact with the Zn anode and C₄F₉SO₃^- entering the Zn²⁺-solvation structure by replacing SO₄^2-. The Zn/Cu cell exhibits a superior average CE of 99.47% over 500 cycles. When coupled with the V₂O₅ cathode, the full cell shows impressive cycle stability. This work provides a simple, effective, and economical solution to the common issues of the Zn anode.