Enhanced NH₄⁺ Removal and Recovery from Wastewater Using Na-Zeolite-based Flow-Electrode Capacitive Deionization:...

Flow-electrode capacitive deionization (FCDI) is a promising electromembrane technology for wastewater treatment and materials recovery. In this study, we used low-cost Na-modified zeolite (Na-zeolite) to prepare a composite flow-electrode (FE) suspension with a small amount of highly conductive carbon black (CB) to remove and recover NH₄⁺ from synthetic and actual wastewater (200 mg-N/L). Compared with conventional activated carbon (AC), the Na-zeolite electrode exhibited a 56.2-88.5% decrease in liquid-phase NH₄⁺ concentration in the FE suspension due to its higher NH₄⁺ adsorption capacity (6.0 vs. 0.2 mg-N/g). The resulting enhancement of NH₄⁺ diffusion to the electrode chamber contributed to the improved performance of FCDI under both constant current (CC) and constant voltage (CV) conditions. The addition of CB to the FE suspension increased the conductivity and facilitated Na-zeolite charging for NH₄⁺ electrosorption, especially in CV mode. NH₄⁺-rich zeolite can be easily separated by sedimentation from CB in the FE suspension, producing a soil conditioner with a high N-fertilizer content suitable for soil improvement and agricultural applications. Overall, our study demonstrates that the novel Na-zeolite-based FCDI can be developed as an effective wastewater treatment technology for both NH₄⁺ removal and recovery as a valuable fertilizer resource.