Electrochemical activation of periodate with graphite electrodes for water decontamination: Excellent applicability...

Advanced oxidation technologies based on periodate (PI, IO₄^-) have garnered significant attention in water decontamination. In this work, we found that electrochemical activation using graphite electrodes (E-GP) can significantly accelerate the degradation of micropollutants by PI. The E-GP/PI system achieved almost complete removal of bisphenol A (BPA) within 15 min, exhibited unprecedented pH tolerance ranging from pH 3.0 to 9.0, and showed more than 90% BPA depletion after 20 h of continuous operation. Additionally, the E-GP/PI system can realize the stoichiometric transformation of PI into iodate, dramatically decreasing the formation of iodinated disinfection by-products. Mechanistic studies confirmed that singlet oxygen (¹O₂) is the primary reactive oxygen species in the E-GP/PI system. A comprehensive evaluation of the oxidation kinetics of ¹O₂ with 15 phenolic compounds revealed a dual descriptor model based on quantitative structure-activity relationship (QSAR) analysis. The model corroborates that pollutants exhibiting strong electron-donating capabilities and high pK_a values are more susceptible to attack by ¹O₂ through a proton transfer mechanism. The unique selectivity induced by ¹O₂ in the E-GP/PI system allows it to exhibit strong resistance to aqueous matrices. Thus, this study demonstrates a green system for the sustainable and effective elimination of pollutants, while providing mechanistic insights into the selective oxidation behaviour of ¹O₂.