Lanthanide Functionalized Covalent Organic Frameworks Hybrid Materials for Luminescence Responsive Chemical Sensing

Covalent organic frameworks (COFs) possess several unique features of structural and functional chemistry, together with other modular photophysical performance, which make them candidates for luminescence responsive chemical sensing. Lanthanide (Ln³⁺ ) functionalized COFs hybrid materials still keep the parent COFs' virtues and also embody the abundant multiple luminescence response with both COFs and Ln³⁺ ions or other guest species. In this review, the summary is highlighted on the lanthanide functionalized COFs hybrid materials and their relevant systems for luminescence responsive chemical sensing. It is subdivided into five sections involving the three main topics. Firstly, the basic knowledges of COFs materials related to the luminescence responsive chemical sensing are introduced (including three sections), involving the chemistry, application and post-synthetic modification (PSM) of COFs, the luminescence and luminescence responsive chemical sensing, and the luminescence responsive chemical sensing of non-lanthanide functionalized COFs hybrids materials. Secondly, the systematic progresses are outlined on the lanthanide functionalized COFs hybrid materials in luminescence responsive chemical sensing, which is the emphasis for this review. Finally, the conclusion and prospect are given.