A critical review of chemical uses in urban sewer systems

Chemical dosing is the most used strategy for sulfide and methane abatement in urban sewer systems. Although conventional physicochemical methods, such as sulfide oxidation (e.g., oxygen/nitrate), precipitation (e.g., iron salts), and pH elevation (e.g., magnesium hydroxide/sodium hydroxide) have been used since the last century, the high chemical cost, large environmental footprint, and side-effects on downstream treatment processes demand a sustainable and cost-effective alternative to these approaches. In this paper, we aimed to review the currently used chemicals and significant progress made in sustainable sulfide and methane abatement technology, including 1) the use of bio-inhibitors, 2) in situ chemical production, and 3) an effective dosing strategy. To enhance the cost-effectiveness of chemical applications in urban sewer systems, two research directions have emerged: 1) online control and optimization of chemical dosing strategies and 2) integrated use of chemicals in urban sewer and wastewater treatment systems. The integration of these approaches offers considerable system-wide benefits; however, further development and comprehensive studies are required.