Ultra-purification of heavy metals and robustness of calcium silicate hydrate (C-S-H) nanocomposites

For the sake of remediating the contamination of heavy metal ions (HMs) that poses high risk to the global environment, a novel inorganic nanocomposite with excellent robustness, calcium silicate hydrate (C-S-H), is synthesized at extremely low cost yet presents rapid adsorption rate and superhigh adsorption capacity. High concentrations of Cu(Ⅱ), Cd(Ⅱ), Co(Ⅱ) and Cr(Ⅲ) in wastewater can be purified to ultra-low level (∼0.008 mg L^-1) within 60 min at low C-S-H dosage, the concentration and pH indexes of which meet the standard for direct discharge in China. The adsorption processes are spontaneous, following the Langmuir adsorption isotherm model, and its kinetics conforms to pseudo-second order model. Meanwhile, C-S-H presents excellent anti-interference performance during the ultra-purification of HMs when exposed to the acid environments, solutions with various HMs as well as high salinity. The ultra-purification of HMs and robustness of C-S-H is realized through multiple mechanisms based on adsorption, involving hydrolysis of HMs, electrostatic interaction, chemical microprecipitation, surface complexation and interlayer complexation, among which interlayer complexation is dominant. All these verify the robust performance and broad applicability of C-S-H to complex aqueous systems.