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Updated: Jul 28, 2025

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Reshaping aromatic frameworks: expansion of aromatic system drives metallabenzenoids to metallapentalenes
Qian Li1, Jiawei Fei1, Kaidong Ruan1
1State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University Xiamen 361005 China.
Abstract:
Reshaping an aromatic framework to generate other skeletons is a challenging issue due to the stabilization energy of aromaticity. Such reconfigurations of aromatics commonly generate non-aromatic products and hardly ever reshape to a different aromatic framework. Herein, we present the transformation of metallaindenols to metallapentalenes and metallaindenes in divergent pathways, converting one aromatic framework to another with an extension of the conjugation framework. The mechanistic study of this transformation shows that phosphorus ligands play different roles in the divergent processes. Further theoretical studies indicate that the expansion of the aromatic system is the driving force promoting this skeletal rearrangement. Our findings offer a new concept and strategy to reshape and construct aromatic compounds.
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