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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.5K
Qualitative Analysis03:46

Qualitative Analysis

22.4K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
22.4K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.8K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.8K
Precipitation of Ions03:11

Precipitation of Ions

28.0K
Predicting Precipitation
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
28.0K
Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

44.2K
The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
44.2K
Chemical Ionization (CI) Mass Spectrometry01:21

Chemical Ionization (CI) Mass Spectrometry

807
The molecular ion peak of a molecule in the mass spectrum provides vital information for molecular identification. However, conventional electron impact ionization can lead to the rapid dissociation of some molecular ions before they reach the detector. A milder ionization method is required to increase the lifetime of such ionized analyte molecules. Chemical ionization (CI) is a gas-phase protonation reaction useful for mass-analyzing analyte molecules that are easily protonated to yield the...
807

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Updated: Jul 28, 2025

Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films
08:12

Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films

Published on: September 8, 2017

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Cesium Methylammonium Lead Iodide (Cs

Yangning Zhang1, Omar F Aly1, Anastacia De Gorostiza1

  • 1McKetta Department of Chemical Engineering and Texas Materials Institute, The University of Texas at Austin, Austin, TX 78712-1062, USA.

Angewandte Chemie (International Ed. in English)
|June 5, 2023
PubMed
Summary
This summary is machine-generated.

Alloying cesium and methylammonium cations in lead iodide perovskite nanocrystals stabilizes their photoactive phase. This cation alloying strategy enhances the stability of iodide-based perovskites for optoelectronic applications.

Keywords:
Cation ExchangeMixed-Cation PerovskitesPerovskite NanocrystalsThermal Stability

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Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation
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Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation

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Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films
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Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation
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Facile Synthesis of Colloidal Lead Halide Perovskite Nanoplatelets via Ligand-Assisted Reprecipitation

Published on: October 1, 2019

13.0K

Area of Science:

  • Materials Science
  • Nanotechnology
  • Solid-State Chemistry

Background:

  • Cesium lead iodide (CsPbI3) and methylammonium lead iodide (MAPbI3) are perovskite materials with promising optoelectronic properties.
  • However, their phase instability, particularly for CsPbI3, limits their practical applications.
  • A-site cation alloying is explored as a method to improve perovskite stability.

Purpose of the Study:

  • To synthesize cesium methylammonium lead iodide (Csx MA1-x PbI3) nanocrystals with varying A-site compositions.
  • To investigate the phase stability and degradation kinetics of these alloyed nanocrystals.
  • To evaluate the effectiveness of A-site cation alloying in stabilizing iodide-based perovskites.

Main Methods:

  • Post-synthetic, room temperature cation exchange between CsPbI3 and MAPbI3 nanocrystals.
  • Characterization of alloyed Csx MA1-x PbI3 nanocrystals, including composition and photoluminescence (PL) tuning.
  • Measurement and modeling of phase transformation and degradation kinetics using an Avrami expression.

Main Results:

  • Successfully obtained Csx MA1-x PbI3 nanocrystals with Cs content up to x = 0.74, retaining the photoactive perovskite phase.
  • Demonstrated composition-tunable photoluminescence (PL) in the alloyed nanocrystals.
  • Observed significantly slower phase transformation and degradation kinetics for alloyed films compared to parent nanocrystals.

Conclusions:

  • A-site cation alloying of cesium and methylammonium is an effective strategy for stabilizing the photoactive perovskite phase in lead iodide nanocrystals.
  • The alloyed Csx MA1-x PbI3 nanocrystals exhibit enhanced phase stability, indicated by slower transformation kinetics.
  • This approach holds promise for developing more stable iodide-based perovskite materials for various applications.