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Updated: Jul 27, 2025

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Published on: July 27, 2022
Design, Synthesis, and Evaluation of Extended C4-Symmetric Dirhodium Tetracarboxylate Catalysts
Zachary J Garlets1, Yannick T Boni1, Jack C Sharland1
1Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322.
Abstract:
The synthesis and evaluation of six C4-symmetric bowl-shaped dirhodium tetracarboxylate catalysts are described. These elaborate high symmetry catalysts are readily generated by means of the self-assembly of four C1-symmetric ligands around the dirhodium core. These catalysts are capable of highly site-selective, diastereoselective and enantioselective C-H functionalization reactions by means of donor/acceptor carbene-induced C-H insertions.
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