Cellulose acetate from lignocellulosic residues: An eco-friendly approach based on a hydrothermal process

The objective of this study was to produce cellulose acetate (CA) from oat (OH) and soybean (SH) hulls through an eco-friendly solvent-and catalyst-free hydrothermal process, and also to compare the acetylation of cellulose by the conventional synthesis process, employing sulfuric acid as the catalyst, and acetic acid as solvent. Cellulose was extracted from OH and SH using a one-step chlorine-free process, resulting in materials with 86 and 81 % cellulose, respectively. CA samples obtained by hydrothermal process had degrees of substitution ranging from 0.95 to 1.47, and from 1.10 to 1.50, for OH and SH samples, respectively, being classified as monoacetates, while the conventional acetylation resulted in cellulose di- and triacetates. The acetylation by the hydrothermal process did not affect cellulose fibers morphology or crystallinity. CA samples obtained by the conventional process showed changes in their surface morphology, with decrease in crystallinity indexes. Viscosimetric average molar mass increased for all modified samples, with mass gain ranging from 16.26 to 519.70 %. The hydrothermal treatment proved to be a promising process for obtaining cellulose monoacetates with some advantages, including short reaction times, it is a one-step process, and lower effluents generation when compared to the conventional processes.