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Updated: Jul 27, 2025

An Experimental Protocol for Femtosecond NIR/UV - XUV Pump-Probe Experiments with Free-Electron Lasers
Published on: October 23, 2018
Theoretical Description of Attosecond X-ray Absorption Spectroscopy of Frenkel Exciton Dynamics
Tim Hansen1, Tatiana Bezriadina1,2, Daria Popova-Gorelova1,2
1I. Institute for Theoretical Physics, Universität Hamburg, Notkestr. 9, 22607 Hamburg, Germany.
Abstract:
Frenkel excitons are responsible for the transport of light energy in many molecular systems. Coherent electron dynamics govern the initial stage of Frenkel-exciton transfer. Capability to follow coherent exciton dynamics in real time will help to reveal their actual contribution to the efficiency of light-harvesting. Attosecond X-ray pulses are the tool with the necessary temporal resolution to resolve pure electronic processes with atomic sensitivity. We describe how attosecond X-ray pulses can probe coherent electronic processes during Frenkel-exciton transport in molecular aggregates. We analyze time-resolved absorption cross section taking broad spectral bandwidth of an attosecond pulse into account. We demonstrate that attosecond X-ray absorption spectra can reveal delocalization degree of coherent exciton transfer dynamics.
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