Preparation of Polymer-Based Nano-Assembled Particles with Fe₃O₄ in the Core

Organic-inorganic nanocomposite particles, possessing defined morphologies, represent the next frontier in advanced materials due to their superior collective performance. In this pursuit of efficient preparation of composite nanoparticles, a series of diblock polymers polystyrene-block-poly(tert-butyl acrylate) (PS-b-PtBA) were initially synthesized using the Living Anionic Polymerization-Induced Self-Assembly (LAP PISA) technique. Subsequently, the tert-butyl group on the tert-butyl acrylate (tBA) monomer unit in the diblock copolymer, yielded from the LAP PISA process, was subjected to hydrolysis using trifluoroacetic acid (CF₃COOH), transforming it into carboxyl groups. This resulted in the formation of polystyrene-block-poly(acrylic acid) (PS-b-PAA) nano-self-assembled particles of various morphologies. The pre-hydrolysis diblock copolymer PS-b-PtBA produced nano-self-assembled particles of irregular shapes, whereas post-hydrolysis regular spherical and worm-like nano-self-assembled particles were generated. Utilizing PS-b-PAA nano-self-assembled particles that containing carboxyl groups as polymer templates, Fe₃O₄ was integrated into the core region of the nano-self-assembled particles. This was achieved based on the complexation between the carboxyl groups on the PAA segments and the metal precursors, facilitating the successful synthesis of organic-inorganic composite nanoparticles with Fe₃O₄ as the core and PS as the shell. These magnetic nanoparticles hold potential applications as functional fillers in the plastic and rubber sectors.