Enhanced Photoluminescence and Random Lasing Emission in TiO₂-Decorated FAPbBr₃ Thin Films

Herein, titanium-dioxide-decorated organic formamidinium lead bromide perovskite thin films grown by the one-step spin-coating method are studied. TiO₂ nanoparticles are widespread in FAPbBr₃ thin films, which changes the optical properties of the perovskite thin films effectively. Obvious reductions in the absorption and enhancements in the intensity of the photoluminescence spectra are observed. Over 6 nm, a blueshift of the photoluminescence emission peaks is observed due to 5.0 mg/mL TiO₂ nanoparticle decoration in the thin films, which originates from the variation in the grain sizes of the perovskite thin films. Light intensity redistributions in perovskite thin films are measured by using a home-built confocal microscope, and the multiple scattering and weak localization of light are analyzed based on the scattering center of TiO₂ nanoparticle clusters. Furthermore, random lasing emission with sharp emission peaks is achieved in the scattering perovskite thin films with a full width at the half maximum of 2.1 nm. The multiple scattering of light, the random reflection and reabsorption of light, and the coherent interaction of light within the TiO₂ nanoparticle clusters play important roles in random lasing. This work could be used to improve the efficiency of photoluminescence and random lasing emissions, and it is promising in high-performance optoelectrical devices.