Enhancing piezocatalytic H₂O₂ production through morphology control of graphitic carbon nitride

Piezocatalytic H₂O₂ production has attracted significant attention as a green alternative to traditional anthraquinone methods with heavy environmental pollution and high energy consumption. However, since the efficiency of piezocatalyst in producing H₂O₂ is poor, searching for a suitable method to improve the yield of H₂O₂ is of great interest. Herein, a series of graphitic carbon nitride (g-C₃N₄) with different morphologies (hollow nanotube, nanosheet and hollow nanosphere) are applied to enhance the piezocatalytic performance in yielding H₂O₂. The hollow nanotube g-C₃N₄ exhibited an outstanding H₂O₂ generation rate of 262 umol·g^-1·h^-1 without any co-catalyst, which is 1.5 and 6.2 times higher than nanosheets and hollow nanospheres, respectively. Piezoelectric response force microscopy, piezoelectrochemical tests, and Finite Element Simulation results revealed that the excellent piezocatalytic property of hollow nanotube g-C₃N₄ is mainly attributed to its larger piezoelectric coefficient, higher intrinsic carrier density, and stronger external stress absorption conversion. Furthermore, mechanism analysis indicated that piezocatalytic H₂O₂ production follows a two-step single-electro pathway, and the discovery of ¹O₂ furnishes a new insight into explore this mechanism. This study offers a new strategy for the eco-friendly manufacturing of H₂O₂ and a valuable guide for future research on morphological modulation in piezocatalysis.