Sustainable Bifunctional ZnO Composites For Synchronous Adsorption And Reduction Of Cr(VI) to Cr(III)

In decentralized systems, adsorption-based strategies offer inherent advantages for the treatment of drinking water contaminated with oxoanion. However, these strategies only involve phase transfer and not the transformation to an innocuous state. The requirement for an after-treatment procedure to manage the hazardous adsorbent further complicates the process. Here we formulate green bifunctional ZnO composites for the simultaneous adsorption and photoreduction of Cr(VI) to Cr(III). Three non-metal-ZnO composites based on raw charcoal- ZnO, modified charcoal- ZnO charcoal, and chicken feather- ZnO were prepared from the combination of ZnO with non-metal precursors. The composites were characterized and both the adsorption and photocatalyst features were studied, separately, in synthetic feedwater and groundwater contaminated with Cr(VI). The adsorption efficiency of the composites for Cr(VI) at different initial concentrations, under solar illumination without hole scavenger, and in the dark without hole scavenger, were appreciable (between 48 and 71%), and initial concentration dependent. The photoreduction efficiencies (PE%) of all the composites were > 70%, irrespective of the initial Cr(VI) concentration. The occurrence of the transformation of Cr(VI) to Cr(III) during the photoredox reaction was established. Whereas the initial solution pH value, organic load, and ionic strength had no influence on the PE (%) of all the composites, CO₃^2- and NO₃^- had negative impacts. The PE (%) values of the different ZnO-composites obtained for both the synthetic feedwater and groundwater systems were comparable.