Who does better for in-situ eutrophic remediation in anoxic environment improvement and nutrient removal: MgO₂ versus...

The long-term insufficient dissolved oxygen (DO), excessive nitrogen (N) and phosphorus (P) have become the main causes of the troublesome eutrophication. Herein, a 20-day sediment core incubation experiment was conducted to comprehensively evaluate the effects of two metal-based peroxides (MgO₂ and CaO₂) on eutrophic remediation. Results indicated that CaO₂ addition could increase DO and ORP of the overlying water more effectively and improve the anoxic environment of the aquatic ecosystems. However, the addition of MgO₂ had a less impact on pH of the water body. Furthermore, the addition of MgO₂ and CaO₂ removed 90.31% and 93.87% of continuous external P in the overlying water respectively, while the removal of NH₄⁺ was 64.86% and 45.89%, and the removal of TN was 43.08% and 19.16%. The reason why the capacity on NH₄⁺ removal of MgO₂ was higher than that of CaO₂ is mainly that PO₄^3- and NH₄⁺ can be removed as struvite by MgO₂. Compared with MgO₂, mobile P of the sediment in CaO₂ addition group was reduced obviously and converted to more stable P. Notably, the microbial community structure of sediments was optimized by MgO₂ and CaO₂, which showed that the relative abundance of anaerobic bacteria decreased and that of aerobic bacteria increased significantly, especially some functional bacteria involved in the nutrient cycle. Taken together, MgO₂ and CaO₂ have a promising application prospect in the field of in-situ eutrophication management.