Augmented photocatalytic degradation of Acetaminophen using hydrothermally treated g-C₃N₄ and persulfate under LED...

Photocatalytic degradation of organic pollutants in water using graphitic carbon nitride and persulfate under visible light (g-C₃N₄/PS system) has been studied. Here, we demonstrate augmentation of photocatalytic degradation of Acetaminophen (AAP) using hydrothermally treated g-C₃N₄ and PS under 400 nm LED irradiation (HT-g-C₃N₄/PS system). A pseudo-first-order rate constant (k_obs, 0.328 min^-1) for degradation of AAP using HT-g-C₃N₄/PS system was determined to be 15 times higher compared to g-C₃N₄/PS system (k_obs, 0.022 min^-1). HT-g-C₃N₄ showed a higher surface area (81 m²/g) than g-C₃N₄ (21 m²/g). Photocurrent response for HT-g-C₃N₄ was higher (1.5 times) than g-C₃N₄. Moreover, Nyquist plot semicircle for HT-g-C₃N₄ was smaller compared to g-C₃N₄. These results confirm effective photoelectron-hole separation and charge-transfer in HT-g-C₃N₄ compared to g-C₃N₄. AAP degradation using HT-g-C₃N₄/PS system was significantly inhibited with $$ and h⁺ scavengers compared to ¹O_2,$$ and $$ scavengers. ESR results revealed $$ formation in HT-g-C₃N₄/PS system. Moreover, photocurrent measurements reveal AAP oxidation by h⁺ of HT-g-C₃N₄ was effective than g-C₃N₄. HT-g-C₃N₄ was reused for five cycles in HT-g-C₃N₄/PS system. Augmented photocatalytic degradation of AAP by HT-g-C₃N₄/PS system compared to g-C₃N₄/PS is attributed to effective photoelectron hole separation of HT-g-C₃N₄ that generates $$ and h⁺ for oxidation of pollutant. Importantly, electrical energy per order (E_EO) was 7.2 kWh m^-3 order^-1. k_obs for degradation of AAP in simulated groundwater and tap water were determined as 0.029 and 0.035 min^-1, respectively. Degradation intermediates of AAP were proposed. AAP ecotoxicity against marine bacteria Aliivibrio fischeri was completely removed after treatment by HT-g-C₃N₄/PS system.