Selective removal of Pb(II) from yellow rice wine using magnetic carbon-based adsorbent

The non-distilled property and prolonged production period of yellow rice wine have significantly increased the metal residue problem, posing a threat to human health. In this study, a magnetic carbon-based adsorbent, named magnetic nitrogen-doped carbon (M-NC), was developed for the selective removal of lead(II) (Pb(II)) from yellow rice wine.

The results showed that the uniformly structured M-NC could be easily separated from the solution, exhibiting a high Pb(II) adsorption capacity of 121.86 mg g^-1 . The proposed adsorption treatment showed significant Pb(II) removal efficiencies (91.42-98.90%) for yellow rice wines in 15 min without affecting their taste, odor, and physicochemical characteristics of the wines. The adsorption mechanism studied by X-ray photoelectron spectroscopy (XPS) and Fourier-transform infrared (FTIR) analyses indicated that the selective removal of Pb(II) could be attributed to the electrostatic interaction and covalent interaction between the empty orbital of Pb(II) and the π electrons of the N species on M-NC. Additionally, the M-NC showed no significant cytotoxicity on the Caco-2 cell lines.

Selective removal of Pb(II) from yellow rice wine was achieved using magnetic carbon-based adsorbent. This facile and recyclable adsorption operation could potentially address the challenge of toxic metal pollution in liquid foods. © 2023 Society of Chemical Industry.